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Showing posts with label statistical mechanics. Show all posts
Showing posts with label statistical mechanics. Show all posts

Thursday, 21 March 2013

Time and Temperature are Complex

Posted on 13:52 by Unknown
In a post from a few days ago, I briefly mentioned the notion of imaginary time with regard to angular momentum. I'd like to go into that a little further in this post.

In 3 spatial dimensions, the flat (Euclidean) metric is $\eta_{ij} = \delta_{ij}$, which is quite convenient, as lengths are given by $(\Delta s)^2 = (\Delta x)^2 + (\Delta y)^2 + (\Delta z)^2$ which is just the usual Pythagorean theorem. When a temporal dimension is added, as in special relativity, the coordinates are now $x^{\mu} = (ct, x_{j})$, and the Euclidean metric becomes the Minkowski metric $\eta_{\mu \nu} = \mathrm{diag}(-1, 1, 1, 1)$ so that $\eta_{tt} = -1$, $\eta_{(t, j)} = 0$, and $\eta_{ij} = \delta_{ij}$. This means that spacetime intervals become $(\Delta s)^2 = -(c\Delta t)^2 + (\Delta x)^2 + (\Delta y)^2 + (\Delta z)^2$, which is the normal Pythagorean theorem only if $\Delta t = 0$. In general, time coordinate differences contribute negatively to the spacetime interval. In addition, Lorentz transformations are given by a hyperbolic rotation by a [hyperbolic] angle $\alpha$ equal to the rapidity given by $\frac{v}{c} = \tanh(\alpha)$. This doesn't look quite the same as normal Euclidean geometry. However, a transformation to imaginary time, called a Wick rotation, can be done by setting $\tau = it$, so $x^{\mu} = (ic\tau, x_{j})$, $\eta_{\mu \nu} = \delta_{\mu \nu}$, $(\Delta s)^2 = (c\Delta t)^2 + (\Delta x)^2 + (\Delta y)^2 + (\Delta z)^2$ as in the usual Pythagorean theorem, and the Lorentz transformation is given by a real rotation by an angle $\theta = i\alpha$ (though I may have gotten some of these signs wrong so forgive me) where $\alpha$ is now imaginary. Now, the connection to the component $L_{(0, j)}$ of the angular momentum tensor should be more clear.

I first encountered this in the class 8.033 — Relativity, where I was able to explore this curiosity on a problem set. That question and the accompanying discussion seemed to say that while this is a cool thing to try doing once, it isn't really useful, especially because it does not hold true in general relativity with more general metrics $g_{\mu \nu} \neq \eta_{\mu \nu}$ except in very special cases. However, as it turns out, imaginary time does play a role in quantum mechanics, even without the help of relativity.

Schrödinger time evolution occurs through the unitary transformation $u = e^{-\frac{itH}{\hbar}}$ satisfying $uu^{\dagger} = u^{\dagger} u = 1$. This means that the probability that an initial state $|\psi\rangle$ ends after time $t$ in the same state is given by the amplitude (whose square is the probability [density]) $\mathfrak{p}(t) = \langle\psi|e^{-\frac{itH}{\hbar}}|\psi\rangle$. Meanwhile, assuming the states $|\psi\rangle$ form a complete and orthonormal basis (though I don't know if this assumption is truly necessary), the partition function $Z = \mathrm{trace}\left(e^{-\frac{H}{k_B T}}\right)$, which can be expanded in the basis $|\psi\rangle$ as $Z = \sum_{\psi} \langle\psi|e^{-\frac{H}{k_B T}}|\psi\rangle$. This, however, is just as well rewritten as $Z = \sum_{\psi} \mathfrak{p}\left(t = -\frac{i\hbar}{k_B T}\right)$. Hence, quantum and statistical mechanical information can be gotten from the same amplitudes using the substitution $t = -\frac{i\hbar}{k_B T}$, which essentially calls temperature a reciprocal imaginary time. This is not really meant to show anything more deep or profound about the connection between time and temperature; it is really more of a trick stemming from the fact that the same Hamiltonian can be used to solve problem in quantum mechanics or equilibrium statistical mechanics.

As an aside, it turns out that temperature, even when measured in an absolute scale, can be negative. There are plenty of papers of this online, but suffice it to say that this comes from a more general statistical definition of temperature. Rather than defining it (as it commonly is) as the average kinetic energy of particles, it is better to define it as a measure of the probability distribution that a particle will have a given energy. Usually, particles tend to be in lower energy states more than in higher energy states, and as a consequence, the temperature is positive. However, it is possible (and has been done repeatedly) under certain circumstances to cleverly force the system in a way that causes particles to be in higher energy states with higher probability than in lower energy states, and this is exactly the negative temperature. More formally, $\frac{1}{T} = \frac{\partial S}{\partial E}$ where $E$ is the energy and $S$ is the entropy of the system, which is a measure of how many different states the system can possibly have for a given energy. For positive temperature, if two objects of different temperatures are brought into contact, energy will flow from the hotter one to the colder, cooling the former and heating the latter until equal temperatures are achieved. For negative temperature, though, if an object with negative temperature is brought in contact with an object that has positive temperature, each object tends to increase its own entropy. Like most normal objects, the latter does this by absorbing energy, but by the definition of temperature, the former does this by releasing energy, meaning the former will spontaneously heat the latter. Hence, negative temperature is hotter than positive temperature; this is a quirk of the definition of reciprocal temperature, so really what is happening is that absolute zero on the positive side is still the coldest possible temperature, absolute zero on the negative side is now the hottest temperature, and $\pm \infty$ is in the middle.

This was really just me writing down stuff that I had been thinking about a couple of months ago. I hope this helps someone, and I also await the day when TV newscasters say "complex time brought to you by..." instead of "time and temperature brought to you by...".
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Posted in class, college, mathematics, MIT, physics, qed, quantum electrodynamics, quantum mechanics, statistical mechanics | No comments

Wednesday, 20 March 2013

Nonzero Electromagnetic Fields in a Cavity

Posted on 08:03 by Unknown
The class 8.06 — Quantum Physics III requires a final paper, written essentially like a review article of a certain area of physics that uses quantum mechanics and that is written for the level of 8.06 (and not much higher). At the same time, I have also been looking into other possible UROP projects because while I am quite happy with my photonic crystals UROP and would be pleased to continue with it, that project is the only one I have done at MIT thus far, and I would like to try at least one more thing before I graduate. My advisor suggested that I not do something already done to death like the Feynman path integrals in the 8.06 paper but instead to do something that could act as a springboard in my UROP search. One of the UROP projects I have been investigating has to do with Casimir forces, but I pretty much don't know anything about that, QED, or [more generally] QFT. Given that other students have successfully written 8.06 papers about Casimir forces, I figured this would be the perfect way to teach myself what I might need to know to be able to start on a UROP project in that area. Most helpful thus far has been my recitation leader, who is a graduate student working in the same group that I have been looking into for UROP projects; he has been able to show me some of the basic tools in Casimir physics and point me in the right direction for more information. Finally, note that there will probably be more posts about this in the near future, as I'll be using this to jot down my thoughts and make them more coherent (no pun intended) for future reference.

Anyway, I've been able to read some more papers on the subject, including Casimir's original paper on it as well as Lifshitz's paper going a little further with it. One of the things that confused me in those papers (and in my recitation leader's explanation, which was basically the same thing) was the following. The explanation ends with the notion that quantum electrodynamic fluctuations in a space with a given dielectric constant, say in a vacuum surrounded by two metal plates, will cause those metal plates to attract or repel in a manner dependent on their separation. This depends on the separation being comparable to the wavelength of the electromagnetic field (or something like that), because at much larger distances, the power of normal blackbody radiation (which ironically still requires quantum mechanics to be explained) does not depend on the separation of the two objects, nor does it really depend on their geometries, but only on their temperatures. The explanation of the Casimir effect starts with the notion of an electromagnetic field confined between two infinite perfectly conducting parallel plates, so the fields form standing waves like the wavefunctions of a quantum particle in an infinite square well. This is all fine and dandy...except that this presumes that there is an electromagnetic field. This confused me: why should one assume the existence of an electromagnetic field, and why couldn't it be possible to assume that there really is no field between the plates?

Then I remembered what the deal is with quantization of the electromagnetic field and photon states from 8.05 — Quantum Physics II. The derivation from that class still seems quite fascinating to me, so I'm going to repost it here. You don't need to know QED or QFT, but you do need to be familiar with Dirac notation and at least a little comfortable with the quantization of the simple harmonic oscillator.

Let us first get the classical picture straight. Consider an electromagnetic field inside a cavity of volume $\mathcal{V}$. Let us only consider the lowest-energy mode, which is when $k_x = k_y = 0$ so only $k_z > 0$, stemming from the appropriate application of boundary conditions. The energy density of the system can be given as \[H = \frac{1}{8\pi} \left(\vec{E}^2 + \vec{B}^2 \right)\] and the fields that solve the dynamic Maxwell equations \[\nabla \times \vec{E} = -\frac{1}{c} \frac{\partial \vec{B}}{\partial t}\] \[\nabla \times \vec{B} = \frac{1}{c} \frac{\partial \vec{E}}{\partial t}\] as well as the source-free Maxwell equations \[\nabla \cdot \vec{E} = \nabla \cdot \vec{B} = 0\] can be written as \[\vec{E} = \sqrt{\frac{8\pi}{\mathcal{V}}} \omega Q(t) \sin(kz) \vec{e}_x\] \[\vec{B} = \sqrt{\frac{8\pi}{\mathcal{V}}} P(t) \cos(kz) \vec{e}_y\] where $\vec{k} = k_z \vec{e}_z = k\vec{e}_z$ and $\omega = c|\vec{k}|$. The prefactor comes from normalization, the spatial dependence and direction come from boundary conditions, and the time dependence is somewhat arbitrary. I think this is because the spatial conditions are unaffected by time dependence if they are separable, and the Maxwell equations are linear so if a periodic function like a sinusoid or complex exponential in time satisfies Maxwell time evolution, so does any arbitrary superposition (Fourier series) thereof. That said, I'm not entirely sure about that point. Also note that $P$ and $Q$ are not entirely arbitrary, because they are restricted by the Maxwell equations. Plugging the fields into those equations yields conditions on $P$ and $Q$ given by \[\dot{Q} = P\] \[\dot{P} = -\omega^2 Q\] which looks suspiciously like simple harmonic motion. Indeed, plugging these electromagnetic field components into the Hamiltonian [density] yields \[H = \frac{1}{2} \left(P^2 + \omega^2 Q^2 \right)\] which is the equation for a simple harmonic oscillator with $m = 1$; this is because the electromagnetic field has no mass, so there is no characteristic mass term to stick into the equation. Note that these quantities have a canonical Poisson bracket $\{Q, P\} = 1$, so $Q$ can be identified as a position and $P$ can be identified as a momentum, though they are actually neither of those things but are simply mathematical conveniences to simplify expressions involving the fields; this will become useful shortly.

Quantizing this yields turns the canonical Poisson bracket relation into the canonical commutation relation $[Q, P] = i\hbar$. This also implies that $[E_a, B_b] \neq 0$, which is huge: this means that states of the photon cannot have definite values for both the electric and magnetic fields simultaneously, just as a quantum mechanical particle state cannot have both a definite position and momentum. Now the fields themselves are operators that depend on space and time as parameters, while the states are now vectors in a Hilbert space defined for a given mode $\vec{k}$, which has been chosen in this case as $\vec{k} = k\vec{e}_z$ for some allowed value of $k$. The raising and lowering operators $a$ and $a^{\dagger}$ can be defined in the usual way but with the substitutions $m \rightarrow 1$, $x \rightarrow Q$, and $p \rightarrow P$. The Hamiltonian then becomes $H = \hbar\omega \cdot \left(a^{\dagger} a + \frac{1}{2} \right)$, where again $\omega = c|\vec{k}|$ for the given mode $\vec{k}$. This means that eigenstates of the Hamiltonian are the usual $|n\rangle$, where $n$ specifies the number of photons which have mode $\vec{k}$ and therefore frequency $\omega$; this is in contrast to the single particle harmonic oscillator eigenstate $|n\rangle$ which specifies that there is only one particle and it has energy $E_n = \hbar \omega \cdot \left(n + \frac{1}{2} \right)$. This makes sense on two counts: for one, photons are bosons, so multiple photons should be able to occupy the same mode, and for another, each photon carries energy $\hbar\omega$, so adding a photon to a mode should increase the energy of the system by a unit of the energy of that mode, and indeed it does. Also note that these number eigenstates are not eigenstates of either the electric or the magnetic fields, just as normal particle harmonic oscillator eigenstates are not eigenstates of either position or momentum. (As an aside, the reason why lasers are called coherent is because they are composed of light in coherent states of a given mode satisfying $a|\alpha\rangle = \alpha \cdot |\alpha\rangle$ where $\alpha \in \mathbb{C}$. These, as opposed to energy/number eigenstates, are physically realizable.)

So what does this have to do with quantum fluctuations in a cavity? Well, if you notice, just as with the usual quantum harmonic oscillator, this Hamiltonian has a ground state energy above the minimum of the potential given by $\frac{1}{2} \hbar\omega$ for a given mode; this corresponds to having no photons in that mode. Hence, even an electrodynamic vacuum has a nonzero ground state energy. Equally important is the fact that while the mean fields $\langle 0|\vec{E}|0\rangle = \langle 0|\vec{B}|0\rangle = \vec{0}$, the field fluctuations $\langle 0|\vec{E}^2|0\rangle \neq 0$ and $\langle 0|\vec{B}^2|0 \rangle \neq 0$; thus, the electromagnetic fields fluctuate with some nonzero variance even in the absence of photons. This relieves the confusion I was having earlier about why any analysis of the Casimir effect assumes the presence of an electromagnetic field in a cavity by way of nonzero fluctuations even when no photons are present. Just to tie up the loose ends, because the Casimir effect is introduced as having the electromagnetic field in a cavity, the allowed modes are standing waves with wavevectors given by $\vec{k} = k_x \vec{e}_x + k_y \vec{e}_y + \frac{\pi n_z}{l} \vec{e}_z$ where $n_z \in \mathbb{Z}$, assuming that the cavity bounds the fields along $\vec{e}_z$ but the other directions are left unspecified. This means that each different value of $\vec{k}$ specifies a different harmonic oscillator, and each of those different harmonic oscillators is in the ground state in the absence of photons. You'll be hearing more about this in the near future, but for now, thinking through this helped me clear up my basic misunderstandings, and I hope anyone else who was having the same misunderstandings feels more comfortable with this now.
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Posted in class, college, electricity, MIT, physics, qed, quantum electrodynamics, quantum mechanics, statistical mechanics, UROP | No comments

Tuesday, 19 February 2013

An Ode to Johnson Noise

Posted on 07:42 by Unknown
This idea for a post has been percolating for a while. I feel like now I am finally ready to share it.
Last semester, in the class 8.13 — Experimental Physics I, one of the experiments that I did was investigating the phenomena of Johnson noise and shot noise and using thes to find, respectively, the Boltzmann constant and electron charge. The other experiments that I did were investigating properties of hydrogen-like atoms through spectroscopy, and determining the speed and decay times of cosmic-ray muons. By far the best and worst experience was with Johnson noise. Follow the jump to read on.

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Posted in class, college, excitement, learning experience, MIT, physics, statistical mechanics | No comments
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